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Assembly has nothing to do with web development. Assembly is one step above binary and you are sending raw commands to the CPU. Even the simplest of programs will have you thinking "wtf?" upon looking at the source. If you are interested in moving from web development to general programming, I would recommend you start with another language first. Java, C, C++, C#, Python, and many others are good. I would say C or C++ if you really wanted to get with the good stuff right away and THEN maybe attempt assembly once you get better.
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